新兴含能材料创制：原子氮聚合物常压合成
（A facile route to synthesize cubic gauche polymeric nitrogen）
Runteng Chen, Jun Zhang, Zelong Wang, Ke Lu, Yi Peng, Jianfa Zhao, Xiaodong Liu, Shaomin Feng, Ruibin Liu, Chuan Xiao, Changqing Jin
Science Bulletin 69(24), 3812 (2024) Runteng Chen, Jun Zhang, Zelong Wang, Ke Lu, Yi Peng, Jianfa Zhao, Shaomin Feng, Changqing Jin
Chin. Phys. Lett. 41, 126102, (2024) (Express Letters)
Highlight: 中科院物理所(IOP)
The cubic gauche polymeric nitrogen (cg-N) consisting of N-N single bond is considered as high energy density materials. The chemical energy of about 800 kJ/mol can be releases when cg-N with N-N single bond decomposes to triple bond nitrogen molecules. In this communication, the long-sought cg-N with N-N single bond has been synthesized for the first time by using a facile route, i.e., thermal-driven-only chemical route at ambient conditions.
