发现镥基富氢高温超导体

Superconductivity above 70 K observed in lutetium polyhydrides

Z. W. Li, X. He, C. L. Zhang, K. Lu, B. S. Min, J. Zhang, S. J. Zhang, J. F. Zhao, L. C. Shi, Y. Peng, S. M. Feng, Z. Deng, J. Song, Q. Q. Liu, X. C. Wang, R. C. Yu, L. H. Wang, Y. Z. Li, J. D. Bass, V. Prakapenka, S. Chariton, H. Z. Liu, and C. Q. Jin

Science China-Physics Mechanics & Astronomy 66, 267411 (2023)

Research Highlight: 中国科学杂志社(SCPMA)

   The binary polyhydrides of heavy rare earth lutetium that shares a similar valence electron configuration to lanthanum have been experimentally discovered to be superconductive. The lutetium polyhydrides were successfully synthesized at high pressure and high temperature conditions using a diamond anvil cell in combinations with the in-situ high pressure laser heating technique. The resistance measurements as a function of temperature were performed at the same pressure of synthesis in order to study the transitions of superconductivity (SC). The superconducting transition with a maximum onset temperature (Tc) 71 K was observed at pressure of 218 GPa in the experiments. The Tc decreased to 65 K when pressure was at 181 GPa. From the evolution of SC at applied magnetic fields, the upper critical field at zero temperature μ0Hc2(0) was obtained to be ~36 T. The in-situ high pressure X-ray diffraction experiments imply that the high Tc SC should arise from the Lu4H23 phase with Pm3n symmetry that forms a new type of hydrogen cage framework different from those reported for previous light rare earth polyhydride superconductors.