发现锆基富氢化物高温超导

Superconductivity in zirconium polyhydrides with Tc above 70K

C. L. Zhang, X. He, Z. W. Li, S. J. Zhang, S. M. Feng, X. C. Wang, R. C. Yu, and C. Q. Jin

Science Bulletin 67, 907 (2022)

Highlight: 中科院物理所(IOP)

   We report the experimental discovery of superconductivity with critical temperature Tc above 70 K in zirconium polyhydrides, the record high so far for transition metal hydrides. The superconducting zirconium polyhydrides are synthesized at the extreme conditions above 200 GPa & 2000 K by using diamond anvil cell combined with in-situ laser heating. Superconductivity was observed in the samples maintained at the same pressure upon quenched from heating. The upper critical field is estimated to be ~36 Tesla from measuring the shift of Tc as function of applied magnetic fields while the superconducting coherent length is calculated to be about 30 ? based on Ginzburg Landau formula.